The Great Stabilizer Showdown: Calcium-Zinc vs. Organotin
For decades, PVC stabilizer additives fell into three main categories, each with distinct pros and cons:
1. -Based Stabilizers (Phasing Out)
Cost: Historically the option (20–30% lower than alternatives).
Toxicity: High environmental and health risks; banned in the EU/US for applications.
Performance: Excellent long-term heat stability; still used in some power cables in developing markets.
2. Calcium-Zinc Stabilizers (Rising Star)
Cost: 15–20% more expensive than , but prices are dropping with scaled production.
Toxicity: Non-toxic, compliant with EU RoHS/REACH, ideal for food packaging and toys.
Limitations: Slightly inferior thermal stability vs. ; requires lubricant co-additives.
3. Organotin Stabilizers (Niche Premium Choice)
Cost: 2–3× higher than calcium-zinc, used where clarity/extreme heat resistance is critical.
Toxicity: Some methyltin types face restrictions, but octyltin is accepted in medical PVC.
Applications: Transparent PVC bottles, medical tubing, and automotive interiors.
Industry Insight: "The move to calcium-zinc PVC stabilizer additives is irreversible in Europe, but in Asia, the transition remains uneven," notes Dr. Lisa Müller, a polymer chemist at Tecnon OrbiChem.
Earth Stabilizers: China’s Homegrown Solution
As Western markets pushed for -free alternatives, China leveraged its abundant earth resources to develop PVC stabilizer additives based on lanthanum and cerium compounds. These stabilizers now dominate segments like
PVC pipes and fittings: Offering heat stability comparable to at competitive costs.
Wire and cable jacketing: earth systems provide electrical insulation.
Product Advantages:
1. Excellent product appearance and fineness.
2. No precipitation, with good moisture resistance.
3. Excellent thermal stability and high retention rate of aging residues.
Application Parameter:
Application | Grade | Appearance | Long-term Heat Stability | Dosage/PHR | Product Feature |
UL105 Degree Electrical Wire | HT6802 | White Powder | ☆☆☆☆ | 5-6 | It can meet the aging requirements of UL70 and UL105 with high cost performance, and it can meet the aging requirements of 136 ℃ for 168 hours. |
UL105 Degree Electrical Wire, VDE Cable | HT6802H | White Powder | ☆☆☆☆☆ | 6-9 | Excellent thermal stability. Aging can meet UL105 degree and VDE cable standards, and it can meet 136 ℃ for 336 hours. |
125 Degree Automotive Wire | HT6802G | White Powder | ☆☆☆☆☆ | 10-12 | Excellent thermal stability, meeting the aging requirements of 150 ℃ for 240 hours. |
Customer Examples of Formula Use:
PVC | Calcium Carbonate | DOTP | Pigment | Stabilizer | Lubricant |
100 | 50 | 50 | Appropriate Amount | 6 | 1.2 |
https://www.zjhongtian.com/product/pvc-calciumzinc-stabilizer/